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131.
Numerical Investigation on 1,3-Butadiene/Propyne Co-pyrolysis and Insight into Synergistic Effect on Aromatic Hydrocarbon Formation 下载免费PDF全文
Tian-yu Li Jia-biao Zou Yan Zhang Chuang-chuang Cao Wei Li Wen-hao Yuan 《化学物理学报(中文版)》2017,30(3):287-294
A numerical investigation on the co-pyrolysis of 1,3-butadiene and propyne is performed to explore the synergistic effect between fuel components on aromatic hydrocarbon formation.A detailed kinetic model of 1,3-butadiene/propyne co-pyrolysis with the sub-mechanism of aromatic hydrocarbon formation is developed and validated on previous 1,3-butadiene and propyne pyrolysis experiments.The model is able to reproduce both the single component pyrolysis and the co-pyrolysis experiments,as well as the synergistic effect between 1,3-butadiene and propyne on the formation of a series of aromatic hydrocarbons.Based on the rate of production and sensitivity analyses,key reaction pathways in the fuel decomposition and aromatic hydrocarbon formation processes are revealed and insight into the synergistic effect on aromatic hydrocarbon formation is also achieved.The synergistic effect results from the interaction between 1,3-butadiene and propyne.The easily happened chain initiation in the 1,3-butadiene decomposition provides an abundant radical pool for propyne to undergo the H-atom abstraction and produce propargyl radical which plays key roles in the formation of aromatic hydrocarbons.Besides,the 1,3-butadiene/propyne co-pyrolysis includes high concentration levels of C3 and C4 precursors simultaneously,which stimulates the formation of key aromatic hydrocarbons such as toluene and naphthalene. 相似文献
132.
Novel Bi2MoO6 Nanosheets/Vertical TiO2 Nanorods Arrays Heterojunction with Enhanced Photoelectrochemical Performance under Visible Light Irradiation 下载免费PDF全文
Xiang Gao Jia-wei Xue Ying Luo Xiao-di Zhu Song Sun Jun Bao Wen-dong Wang 《化学物理学报(中文版)》2017,30(5):576-580
Novel Bi2MoO6/TiO2 heterojunction was fabricated by growing Bi2MoO6 nanosheets arrays on the vertically aligned TiO2 nanorods arrays via a two-step solvothermal method. The obtained Bi2MoO6/TiO2 hierarchical heterojunction showed excellent visible light photoelectrochemical performance. Compared with the pure TiO2 and Bi2MoO6, the photocurrent density of the heterojunction was increased 57 and 29 times, respectively. Furthermore, the hydrogen generation rate of the Bi2MoO6/TiO2 for photoelectrocatalytic water-splitting was about 6 times higher than that of the pure Bi2MoO6. The improved performance can be attributed to the synergistic effects of enhanced absorption of visible light, increase of migration rate and separation efficiency of photo-induced carriers. 相似文献
133.
134.
In recent years, increasing attention has been paid to “soft” photoionization (PI), which will potentially become a standard, universal ionization method. Tunable synchrotron vacuum ultraviolet (SVUV) light, a quasi-continuous light with good energy resolution and high photon flux, has proved an ideal source for “soft” PI in various research fields (e.g., combustion chemistry and molecular imaging).This review focuses on combinations of SVUV light with commonly used techniques (e.g., molecular-beam sampling, laser desorption, ion desorption, and thermal vaporization). These couplings have successful applications in flame chemistry, organic analysis, chemical imaging and aerosol mass spectrometry. 相似文献
135.
利用扩展X射线吸收精细结构光谱(EXAFS)研究了不同掺杂浓度Nd3+:Lu2O3纳米粉体和透明陶瓷中Nd3+的局域结构.结果表明,在不同条件下Nd3+均以固溶取代Lu3+的方式进入Lu2O3基质晶格,掺杂Nd3+原子的第一配位键长约为0.225 nm,小于Nd2O3纳米粉中Nd-O第一近邻键长0.251 nm,而大于... 相似文献
136.
Cao L Wang YZ Chen TX Zhang WH Yu XJ Ibrahim K Wang JO Qian HJ Xu FQ Qi DC Wee AT 《The Journal of chemical physics》2011,135(17):174701
Charge transfer dynamics across the lying-down 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) organic semiconductor molecules on Au(111) interface has been investigated using the core-hole clock implementation of resonant photoemission spectroscopy. It is found that the charge transfer time scale at the PTCDA∕Au(111) interface is much larger than the C 1s core-hole lifetime of 6 fs, indicating weak electronic coupling between PTCDA and the gold substrate due to the absence of chemical reaction and∕or bonding. 相似文献
137.
Chen Li Wendong Wang Congying Xu Yuanxu Liu Bo He Chusheng Chen .CAS Key Laboratory of Materials for Energy Conversion University of Science Technology of China Hefei Anhui China 《天然气化学杂志》2011,(4):345-349
The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible(Fe2+,Mo6+) and (Fe3+,Mo5+)valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies. 相似文献
138.
Wang X Qi Z Wang S Liu G Gao H Tian Y 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(5):1660-1662
In order to investigate gastric cancer at cellular and sub-cellular level, a single human gastric adenocarcinoma BGC823 cell was studied by an infrared microscope equipped with a focal plane array (FPA) detector. The spectra showed difference between the nucleus and the endoplasmic reticulum (ER) of the BGC823 cell. The peak of vasPO2- was shifted to a higher wavenumber at the nucleus compared with that at the ER. The height ratios of 2954 cm(-1)/2922 cm(-1) (CH3/CH2) and 1088 cm(-1)/1539 cm(-1) (DNA/amide II) of the nucleus were significantly higher than those of the ER. Furthermore, chemical images reveal the intensity distributions of lipids, proteins and DNA of the single BGC823 cell, and the intense absorptions of proteins and DNA were observed in the nuclear region of the cell while the intense absorption of lipids was found in the ER region of the cell. The Fourier transform infrared (FTIR) microspectroscopic imaging result indicates the study of the single gastric cancer cell at sub-cellular level can be beneficial for knowing gastric cancer more which will be of great importance for the study and diagnosis of gastric cancer. The result also suggests that FPA is a useful tool in the study of a single cell and may be a powerful tool for study and diagnosis of gastric cancer. 相似文献
139.
Sun S Ding J Bao J Luo Z Gao C 《Combinatorial chemistry & high throughput screening》2011,14(3):160-172
The last decade has seen significant progresses in the application of combinatorial approaches and high-throughput screening in photocatalyst discovery. This paper aims at providing a comprehensive review on the parallel synthesis and high-throughput characterization of photocatalysts, including the development of instrumentation, strategy of experiment, preparation of libraries, high-throughput screening technique and data analysis. The review ends with a summary of the remaining challenges and prospects on combinatorial photocatalyst discovery. 相似文献
140.
Zhou S Chu G Cao L Shan X Liu F Han JG Sheng L 《European journal of mass spectrometry (Chichester, England)》2011,17(2):101-112
The photoionization and photodissociation of L-valine are studied by tunable synchrotron vacuum ultraviolet photoionization mass spectrometry at the photon energy of 13 eV. The ionization energy of L-valine and the appearance energies of major fragments are measured by the photoionization efficiency spectrum in the photon energy range of 8-11 eV. Possible formation pathways of the major fragments, NH(2)CHC(OH)(2)(+) (m/z=75), NH(2)(CH(3))(2)(CH)(2)(+) (m/z=72) and NH(2)CHCO(+) (m/z=57), are discussed in detail with the theoretical calculations at the B3LYP/6-31++G (d, p) level. Hydrogen migration is considered as the key way for the formation of NH(2)CHC(OH)(2)(+) (m/z=75) and NH(2)CHCO(+) (m/z=57). Furthermore, other fragments, NH(2)CHCOOH(+) (m/z=74), (CH(3))(2)(CH)(2)(+) (m/z=56), C(4)H(7)(+) (m/z=55), NH(2)CHOH(+) (m/z=46), NH(2)CH(2)(+) (m/z=30) and m/z=18, species are also briefly described. 相似文献